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805,807,808 This framework exploits the fact that late 3d -block divalent transition metal complexes formed with biological ligands, even complexes of considerable thermodynamic stability and metal association constants of 10 10 to ≥10 20 M –1 , are kinetically exchange-labile, 809 particularly so if a higher coordination number complex can be transiently formed during the metal transfer process (Figure 34, top )